A hybrid electrochromic (HEC) device was constructed from optically active nanocrystalline WO3 film and transparent platinised SnO2Č F-glass electrodes encapsulating a gel redox electrolyte. The electrolyte was prepared from an organic-inorganic ICS-PPG precursor that was synthesized from bis end-capped triethoxy silane and poly(propyleneglycol)- bis-(2-amino- propyl) ether (MW = 4000). KI and I-2 in a molar ratio KIČ I-2 = 10Č 1 were a source of an I-3(-)žI- redox pair while valeric acid was used as a catalyst for the solvolysis reactions of the ICS-PPG precursor. The stability and kinetics of colouringžbleaching changes of the HEC device were determined by using in-situUV-visible spectroelectrochemical measurements between + 2 and - 2 V (CV, CC).

Rights

URN

URN:NBN:SI:DOC-QXU0SXTI

COBISSID

2956826

Added

16.09.2009

Metadata

Citation

APA:

Surca, Angelja Kjara, Orel, Boris, Colomban, Philippe (2003). In-situ resonance Raman measurements of a hybrid electrochromic cell with a gel redox I3-/I- electrolyte. Acta chimica slovenica, volume 50, issue 4, str. 601-618. URN:NBN:SI:DOC-QXU0SXTI from http://www.dlib.si

MLA:

Surca, Angelja Kjara, Orel, Boris, Colomban, Philippe. "In-situ resonance Raman measurements of a hybrid electrochromic cell with a gel redox I3-/I- electrolyte." Acta chimica slovenica volume 50. issue 4 (2003) str. 601-618.
<http://www.dlib.si/?URN=URN:NBN:SI:DOC-QXU0SXTI>

Acta chimica slovenica
1993-
(Assembly record)

In-situ resonance Raman measurements of a hybrid electrochromic cell with a gel redox I3-/I- electrolyteIn-situ resonančni ramanski spektri hibridnih elektrokromnih celic z gelskim (I3-/I-) elektrolitom

In-situ resonance Raman measurements of a hybrid electrochromic cell with a gel redox I3-/I- electrolyte
In-situ resonančni ramanski spektri hibridnih elektrokromnih celic z gelskim (I3-/I-) elektrolitom