T. WEGRZYN et al.: IMPACT TOUGHNESS OF WMD AFTER MAG WELDING WITH MICRO-JET COOLING 1001–1004 IMPACT TOUGHNESS OF WMD AFTER MAG WELDING WITH MICRO-JET COOLING UDARNA @ILAVOST WMD PO MAG VARJENJU Z MIKRO-JET HLAJENJEM Tomasz Wegrzyn1, Jan Piwnik2, Aleksander Borek3, Agnieszka Kurc-Lisiecka4 1Silesian University of Technology, Faculty of Transport, Krasiñkiego 8, 40-019 Katowice, Poland 2Bialystok University of Technology, Mechanical Faculty, Wiejska 45c, 16-351 Bialystok, Poland 3Plasma-system, Towarowa 14, 41-103 Siemianowice Œl¹skie, Poland 4University of D¹browa Górnicza, Rail Transport Department, Cieplaka 1c, 41-300 D¹browa Górnicza, Poland a.kurc@wp.pl Prejem rokopisa – received: 2015-06-30; sprejem za objavo – accepted for publication: 2015-11-05 doi:10.17222/mit.2015.159 The MAG welding process with micro-jet cooling of the weld during the cooling stage was investigated. For micro-jet gases the mixtures of argon with carbon dioxide, oxygen, and nitrogen were tested. This paper presents a piece of information about a new proposal for gas mixtures during micro-jet cooling after welding. Presented is the main information about the influence of various micro-jet gas mixtures on the metallographic structure of the weld metal. The mechanical properties of the welds were presented in terms of various gas mixtures selection for micro-jet cooling. The influence of argon gas mixtures with oxygen and nitrogen for micro-jet cooling after welding are reported for the first time in the technical literature. Keywords: welding, micro-jet cooling, weld, metallographic structure, gas mixtures, GMA welding Preiskovana je bila za~etna faza postopka MAG varjenja z mikro-jet hlajenjem zvara. Za mikro-jet so bile preizku{ene me{anice argona z ogljikovim dioksidom, kisikom in du{ikom. ^lanek predstavlja del informacije o predlogu novih me{anic plinov za mikro-jet hlajenje po varjenju. Dane so informacije o vplivu razli~nih plinskih me{anic za mikro-jet na metalografske strukture zvarjenega materiala. Mehanske lastnosti zvarov so prikazane v smislu izbranih razli~nih vrst me{anic plinov za mikro-jet hlajenje. Vpliv me{anice argona s kisikom in du{ikom za mikro-jet hlajenje po varjenju je prvi~ prikazan tudi v tehni{ki literaturi. Klju~ne besede: varjenje, mikro-jet hlajenje, zvar, metalografska struktura, me{anice plinov, GMA varjenje 1 INTRODUCTION MAG is an important industrial welding process, preferred for its versatility, speed and the relative ease of adapting the process to robotic automation. Develop- ments in arc welding processes are strongly related with the need to increase productivity without losing the quality of the weld.1–5 The reduction of costs and com- petitive pricing are each day more strongly related with technological innovations.6–11 The properties of steel welded structures depend on many factors such as weld- ing technology, filler materials, state of stress. The main role of these conditions is also connected with the ma- terials, the chemical composition of steel and the weld metal deposit (WMD).12–16 The chemical composition of metal weld deposit could be regarded as a very important factor influencing the properties of the weld metal deposit (WMD). In particular, the oxygen, titanium, manganese and aluminium are regarded as the main elements that positively effect the mechanical properties and the metallographic structure of low-alloy welds. This is because of the non-metallic inclusions in weld (Figure 1) that have similar lattice parameter as the ferrite (TiO, TiN, MnO, Al2O3). Materiali in tehnologije / Materials and technology 50 (2016) 6, 1001–1004 1001 UDK 620.178.2:621.791:621.78.08 ISSN 1580-2949 Professional article/Strokovni ~lanek MTAEC9, 50(6)1001(2016) Figure 1: a) SEM micrographs showing the oxide inclusions in low-alloy WMD after welding with basic electrodes and b) EDS anal- ysis of the WMD1 Slika 1: a) SEM-posnetek prikazuje oksidne vklju~ke v malo legi- ranem WDM po varjenju z bazi~nimi elektrodami in b) EDS analiza WMD1 The welding parameters, metallographic structure and chemical composition of the weld metal deposit are regarded as important factors that influence the impact toughness properties of the deposits.9–12 In a typical low- alloy steel weld structure the best mechanical properties correspond with the maximum amount of acicular ferrite (AF) in the weld metal deposit (WMD) and the mini- mum amount of MAC phases (self-tempered martensite, retained austenite, carbide). This article focuses on mild-steel welding and covers the new possibilities of that method. Since 2011, innovative welding technology based on micro-jet cooling just after welding has been investigated. The weld metal deposit (WMD) was carried out for the standard MAG process and for the innovative welding method with micro-jet cooling. A very high per- centage of acicular ferrite (AF) in WMD was obtainable (55–73 %) for low-alloy steel welding only for micro-jet cooling after the MIG process with argon or helium.13–18 Argon and helium, as micro-jet gases, could provide a better impact toughness of the WMD (0.08 % C, 0.8 % Mn) than in the case of the classic MAG process (Table 1). Table 1 shows that argon is a more beneficial micro- jet cooling gas than helium. Also, it is shown that micro-jet cooling improves the amount of acicular ferrite in the weld. Helium is not such a beneficial micro-jet gas as argon and its mixtures in the MAG process (because of the high percentage of MAC phases). In that paper gas mixtures of argon with a small amount of oxygen and nitrogen were mainly tested because of the positive influ- ence of some oxide and nitride inclusions of acicular ferrite forming and thus the very good impact toughness of the welds. Table 1: Metallographic structure of MAG welds1 Tabela 1: Metalografske strukture MAG zvarov1 Micro-jet gases Ferrite AF MAC phases without micro-jet 43% 4% He 59% 6% Ar 63% 2% 2 EXPERIMENTAL PART The weld metal deposit was prepared by welding with micro-jet cooling with gas mixtures both for the standard MAG process and the MAG welding with micro-jet cooling. The MAG welding process was based on a shielded gas mixture of 79 % Ar and 21 % CO2. To obtain various amounts of acicular ferrite in the WMD the installed micro-jet injector was close to the MAG welding head. The main parameters of the micro-jet cooling were slightly varied: • cooling steam diameter (40 μm and 50 μm), • gas pressure (0.4 MPa and 0.5 MPa), • gas mixtures of argon (82 % Ar/18 % CO2 and 98 % Ar/2 % O2 and 98 % Ar + 2 % N2) were chosen as the micro-jet gases. A montage of the welding head and the micro-jet injector is illustrated in Figure 2. The main data about the parameters of the welding are shown in Table 2. The weld metal deposit was prepared by welding with micro-jet cooling using a larger number of parameters (Table 3). Table 2: Parameters of the welding process Tabela 2: Parametri procesa varjenja No. Parameter Value 1. Diameter of wire 1.2 mm 2. Standard current 220 A 3. Voltage 24 V 4. Shielding welding gases 82% Ar/18% CO2 5. Kind of tested micro-jetcooling gases Ar, 82% Ar/18% CO2; 98% Ar/2% O2; 98% Ar/2% N2 6. Gas pressure 0.4 MPa; 0.5 MPa 7. Number of micro-jets 1 8. Cooling stream diameter 40 μm; 50 μm Table 3: Chemical composition of WMD Tabela 3: Kemijska sestava WDM Comment Element Amount in all tested cases C 0.08% in all tested cases Mn 0.79% in all tested cases Si 0.39% in all tested cases P 0.017% in all tested cases S 0.018% 3 RESULTS AND DISCUSSION We tested and compared various welds of the stan- dard MAG process connected with those of the innova- tive micro-jet cooling. A typical weld metal deposit had a similar chemical composition in all the tested cases. The micro-jet gas could only have an influence on more or less intensive cooling conditions, but it does not have any influence on the chemical WMD composition (Table 3), except for the oxygen and nitrogen amounts in the WMD (Table 4). It is easy to deduce that the amount of oxygen and nitrogen was slightly increased in terms of the chemical composition of the micro-jet gas mixtures. After the che- mical analyses the metallographic structure of the WMD T. WEGRZYN et al.: IMPACT TOUGHNESS OF WMD AFTER MAG WELDING WITH MICRO-JET COOLING 1002 Materiali in tehnologije / Materials and technology 50 (2016) 6, 1001–1004 Figure 2: Montage of welding head and micro-jet injector (on the right) Slika 2: Namestitev varilne glave in mikro-jet injector (na desni) (with and without micro-jet cooling) was carried out. An example of this structure was shown in Table 5. Table 4: Content of oxygen and nitrogen in WMD Tabela 4: Vsebnost kisika in du{ika v WMD Micro-jet gases Element Amount (%) Ar O 0.0350 82% Ar / 18% CO2 O 0.0380 98% Ar / 2% O2 O 0.0380 98% Ar / 2% N2 O 0.0350 Ar N 0.0055 82% Ar / 18% CO2 N 0.0055 98% Ar / 2% O2 N 0.0055 98% Ar / 2% N2 N 0.0060 Table 5: Metallographic structure of (MAG method 82% Ar/18% CO2) welds Tabela 5: Metalografska struktura zvarov (metoda MAG z 82 % Ar/18 % CO2) Micro-jet gas Gas pressure, MPa Cooling steam diameter, μm Ferrite AF MAC phases without micro-jet - - 55% 3% Ar 0.4 40 60% 2% Ar 0.4 50 63% 2% Ar 0.5 40 63% 2% Ar 0.5 50 61% 2% 98% Ar/2% O2 0.4 40 64% 2% 98% Ar/2% O2 0.4 50 66% 2% 98% Ar/2% O2 0.5 40 67% 2% 98% Ar/2% O2 0.5 50 65% 2% 82% Ar/18% CO2 0.4 40 58% 2% 82% Ar/18% CO2 0.4 50 60% 2% 82% Ar/18% CO2 0.5 40 61% 2% 82% Ar/18% CO2 0.5 50 59% 3% 98% Ar/2% N2 0.4 40 58% 2% 98% Ar/2% N2 0.4 50 59% 2% 98% Ar/2% N2 0.5 40 59% 2% 98% Ar/2% N2 0.5 50 57% 3% Table 5 shows that in all cases a gas mixture of argon with oxygen is the most beneficial choice. We also ob- served MAC (self-tempered martensite, retained auste- nite, carbide) phases on various levels. In the standard MAG welding process (without micro-jet cooling) there are usually gettable larger amounts of grain-boundary ferrite (GBF) and site-plate ferrite (SPF) fraction, mean- while in micro-jet cooling WMD both of the GBF and SPF structures were not so dominant. Ferrite with a percentage above 60 % was gettable only in one case after MAG welding with micro-jet gas mixtures: argon/oxygen or argon/carbon dioxide (Figure 3). The larger amount of MAC phases was especially gettable for the more intensive micro-jet cooling with a gas mixture of argon-oxygen (Tables 5 and 6). The heat-transfer coefficient of the various micro-jet gas mixtures influences the cooling conditions of the welds (and consequently the rise in the content of the MAC phases). This is due to the conductivity coefficients ( ·105), as shown in Table 6. Table 6: Heat-transfer coefficient of various gases used in micro-jet cooling Tabela 6: Koeficient prenosa toplote razli~nih plinov, uporabljenih pri mikro-jet hlajenju Gas Conductivity coefficients,mW/mK Ar 17.9 CO2 16.8 O2 26.3 N2 26 He 156.7 Table 7: Metallographic structure of MAG (82 % Ar/18 % CO2) welds Tabela 7: Metalografska struktura MAG zvarov (82 % Ar/18 % CO2) Welding method Micro-jetgas Test temperature, °C Impact toughness KCV, J MAG without -40 below 40 MAG with micro-jet cooling Ar -40 55 MAG with micro-jet cooling 82% Ar/ 18% CO2 -40 53 MAG with micro-jet cooling 98% Ar/ 2% O2 -40 57 MAG with micro-jet cooling 98% Ar/ 2% N2 -40 below 40 MAG without +20 177 MAG with micro-jet cooling Ar +20 191 MAG with micro-jet cooling 82% Ar/ 18% CO2 +20 189 MAG with micro-jet cooling 98% Ar/ 2% O2 +20 194 MAG with micro-jet cooling 98% Ar/ 2% N2 +20 183 Analysing Table 6, it is possible to deduce that helium could give the strongest cooling conditions, but helium was not tested in this investigation. The cooling T. WEGRZYN et al.: IMPACT TOUGHNESS OF WMD AFTER MAG WELDING WITH MICRO-JET COOLING Materiali in tehnologije / Materials and technology 50 (2016) 6, 1001–1004 1003 Figure 3: Microstructure weld metal with large amount of acicular ferrite in weld (67 %) after Ar/CO2 micro-jet cooling Slika 3: Mikrostruktura zvara z velikim dele`em igli~astega ferita v zvaru (67 %), po mikro-jet hlajenju z Ar/CO2 conditions after welding using other micro-jet gases are on a similar level. After the microscope tests, the Charpy V impact toughness of the deposited metal was assessed with 5 specimens. The Charpy tests were carried out at temperatures of –40 °C and +20 °C only. The impact toughness results are given in Table 7. It is easy to deduce that the impact toughness, espe- cially at the negative temperature of the weld metal deposit, is apparently affected by the kind of micro-jet cooling gas mixtures. Micro-jet technology always strongly improves the impact toughness of the WMD. Argon with oxygen and argon with carbon dioxide must be treated as good choices. Argon as the main element of the gas mixture with a small amount of oxygen gives better results than gas mixtures of argon with carbon dioxide and argon with nitrogen. Nevertheless, micro-jet cooling with gas mixture of argon with 2 % of nitrogen gives better results than the simple MAG welding without micro-jet cooling. This can be explained by the presence of nitride inclusions in the weld (for instance TiN) that facilitate the nucleation of ferrite AF. 4 CONCLUSIONS In low-alloy steel welding there are two general types of tests performed: impact toughness and structure. Aci- cular ferrite and MAC phases (self-tempered martensite, upper and lower bainite, retained austenite, carbides) were analysed and counted for each weld metal deposit. These two tests (microstructure and impact toughness) proved that micro-jet technology gives a beneficial modi- fication to the mechanical properties of the welds. The innovative micro-jet technology was firstly recognized with great success for MIG welding only with argon as a micro-jet gas. In this paper micro-jet cooling technology was for the first time described and tested for MAG welding process with various micro-jet gas mixtures of argon. Final conclusions: • micro-jet cooling could be treated as an important element of MAG welding process, • micro-jet cooling after welding can improve the amount of ferrite AF, the most beneficial phase in low-alloy steel WMD, • gas mixture of argon with carbon dioxide and gas mixture of argon with oxygen could be treated as better micro-jet cooling media than gas mixture of argon with nitrogen, • micro-jet cooling after welding can seriously improve the impact toughness of low-alloy steel WMD, • micro-jet cooling after welding practically does not have an influence on the MAC amount in low-alloy steel WMD. 5 REFERENCES 1 T. Wêgrzyn, Gas mixtures for welding with micro-jet cooling, Arch. Metall. 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