F. LIU et al.: STUDY OF DROPLET TRANSFER CHARACTERISTICS AND WELD FORMATION WITH ER430LNb ... 241–248 STUDY OF DROPLET TRANSFER CHARACTERISTICS AND WELD FORMATION WITH ER430LNb FERRITIC STAINLESS STEEL DURING GAS METAL ARC WELDING PREIZKUS LASTNOSTI PRENOSA KAPLJIC TALINE IN NASTAJANJA ZVARA FERITNEGA JEKLA VRSTE ER430LNB MED OBLO^NIM VARJENJEM V TOKU PLINSKE ME[ANICE KISIKA IN ARGONA Feng Liu 1 ,Y uGu 2 , Fanghong Xu 2 , Han Zhang 1 , Shaowei Xu 1 , Zhihang Yan 1 , Zhifeng Yan 1 , Wenxian Wang 1* 1 College of Materials Science and Engineering, Taiyuan University of Technology, 79 West Yingze Street, Taiyuan 030024, Shanxi Province, China 2 Shanxi Taigang Stainless Steel Co., Ltd., Taiyuan 030003, China Prejem rokopisa – received: 2022-11-26; sprejem za objavo – accepted for publication: 2023-03-16 doi:10.17222/mit.2022.697 An ER430LNb ferritic stainless steel wire was used for a gas metal arc welding (GMAW) test. The characteristics of droplet transfer and its corresponding voltage and current waveforms were investigated using a high-speed camera and synchronous ac- quisition of electrical signals. The weld formation, droplet transfer patterns and corresponding microstructures under different welding parameters were observed, and the effect of the current level on the droplet transfer frequency was discussed. As the re- sults show, there were three typical metal transfer patterns during the GMAW using the ER430LNb ferritic stainless steel wire, namely short circuit transfer, mix transfer and spray transfer. With an increase in the welding current, the weld formation is changing constantly, and the droplet transfer frequency increases exponentially. With the change in the transfer pattern, the co- lumnar ferrite structure of the weld is continuously coarsening. In addition, hardness measurements were taken on joints welded at different welding currents for comparison. Keywords: ER430LNb ferritic stainless steel wire, droplet transfer, weld formation, hardness Za preizkuse oblo~nega varjenja v toku plinske me{anice kisika in argona (GMAW; angl:: gas metal arc welding) so uporabili `ico iz nerjavnega feritnega jekla ER430LNb. S pomo~jo uporabe sistema za opazovanje s hitro kamero in sinhronega zajemanja elektri~nih signalov so raziskovali lastnosti prenosa kapljic taline ter odgovarjajo~e napetostno in tokovno obliko valov. Med preizkusi so opazovali in nato obravnavali nastajanje zvara, vzorcev prenosa kapljic taline in nastanka odgovarjajo~e mikrostrukture pri razli~nih izbranih parametrih varjenja. Rezultati preizkusov in opazovanj so pokazali, da potekajo trije tipi~ni vzorci prenosa kapljic taline pri GMAW z uporabo `ice iz nerjavnega feritnega jekla ER430LNb in sicer: kratko sti~ni prenos, me{ani prenos in prenos v obliki razpr{ila. Z nara{~ajo~im varilnim tokom se nastajanje zvara konstantno spreminja in frekvenca prenosa kapljic taline nara{~a eksponentno. S spremembo vzorca prenosa taline stebri~asta feritna struktura zvara kontinuirno postaja bolj groba. Dodatno so s pomo~jo meritev trdote zvarnih spojev medsebojno primerjali njihove lastnosti glede na izbrane parametre varjenja. Klju~ne besede: varilna `ica iz feritnega jekla vrste ER430LNb, prenos kapljic taline, nastajanje zvara, trdota 1 INTRODUCTION Ferritic stainless steels are widely used in various ar- eas, including automobile manufacturing, white goods and nuclear power industries, as they exhibit a good combination of ductility, thermal conductivity and corro- sion resistance. Their cost is also relatively lower and more stable than those of austenitic grades as they do not contain any nickel. 1–3 As a relatively new type of engi- neering material, ER430LNb ferritic stainless steel with excellent comprehensive properties is produced by par- tially or completely replacing nickel with niobium to re- duce the alloying-element costs. Deardo et al. 4 pointed out that the precipitation of NbC, NbN, Fe 2 Nb and other intermetallic compounds formed in steel by Nb, a strong carbide-forming element, significantly improved the me- chanical properties of ER430LNb at high temperatures, 5,6 effectively prevented the intergranular chromium poverty caused by the precipitation of carbon-chromium com- pounds, and improved the resistance to intergranular cor- rosion. 7 Different forms of droplet transfer have various con- sequences for the stability of the welding arc, the depth of fusion of the weld, spatter and the generation of de- fects and they affect the quality of the weld-seam forma- tion. Oscillography and high-speed camera technology are two of the main experimental tools used for studying droplet transfers. 8 Oscillography records the waveform of the welding current and arc voltage during a welding process and indirectly researches the droplet transfer based on the waveform modification. A high-speed cam- Materiali in tehnologije / Materials and technology 57 (2023) 3, 241–248 241 UDK 669.15-194.57:621.791.75 ISSN 1580-2949 Original scientific article/Izvirni znanstveni ~lanek MTAEC9, 57(3)241(2023) *Corresponding author's e-mail: wangwenxian@tyut.edu.cn (Wenxian Wang) era captures the welding arc zone with a high-speed video; a droplet-transfer process is recorded, and through an analysis of droplet transfer images we directly investi- gate the characteristics of the droplet transfer. The com- bination of oscillography and a high-speed camera al- lows us to better investigate the characteristics of a droplet transfer. The droplet transfer of GMAW has been extensively studied by domestic and international schol- ars. Luo et al. 9 discussed the relationship between the droplet-transfer behavior and arc current-voltage signal and found that the characteristics of the droplet-transfer behavior depend on the arc current-voltage signal. Neyka et al. 10 investigated the droplet-transfer behavior of Tandam based on the high-speed camera technology. Simpson et al. 11 showed theoretically that when the welding current is less than 250 A, the shape of the drop- let is approximately spherical. Praveen et al. 12 combined a high-speed camera and oscillography to research drop- let-transfer patterns during a pulsed-welding process. Hu and Tsai et al. 13 investigated the droplet-transfer behavior at constant and pulsed currents through numerical simu- lations, indicating that the higher the welding current, the greater is the electromagnetic force on the droplet and the easier is the droplet transfer from the wire to the base material. It was also found that the higher the welding current, the smaller is the droplet diameter and the higher is the droplet transfer frequency. Therefore, this work investigates the droplet transfer characteristics and weld formation of stainless steel in an GMAW process. The droplet transfer frequency, micro- structure and hardness of joints welded at different weld- ing currents were studied for comparison. The results of the study lay the foundation for the subsequent process optimization of the gas-shielded welding of ER430LNb ferritic stainless steel. 2 EXPERIMENTAL PROCEDURE The experimental system for the research of the GMAW using an ER430LNb ferritic stainless steel wire is shown in Figure 1; it mainly includes a robotic GMAW system and a synchronous acquisition of droplet transfer and electrical parameters. The robotic GMAW system includes a welding robot and its control cabinet, welding power supply, gas supply system and working platform to provide a stable droplet-transfer process. The electrical-signal synchronous acquisition system includes a high-speed camera, xenon light source and Hanover analyzer to capture the images and electrical signals of the droplet-transfer process in real time. A 6-axis OTC AX-V6 welding robot and YD-500GL3 welding power source are utilized to sustain stable arc burning. A MIX-L25 gas-mixture cabinet adjusts the content of ar- gon and oxygen. The CR3000×2 high-speed camera op- erating at 3000 fps in the same line as the 1000 W xenon lamp light source generator and the welding torch remain relatively stationary. The AH19 Hanover analyzer ac- quires the data from the characteristic signals of voltage and current during the welding process. The base material (BM) included 4.0 mm thick plates of AISI 430 ferritic stainless sheets and the welding wire was an ER430LNb ferritic stainless steel wire with a di- ameter of 1.2 mm. Table 1 lists the main components of the welding wire and the base metal. Meanwhile, the welding parameters are listed in Table 2. The welding current was the crucial research variable in this work. The welding speed was selected in a range of 10–100 cm/min. The wire feed speed (WFS) was auto- matically matched with the GMAW power supply ac- cording to the welding current. But the welding current and arc voltage can be adjusted independently. To sim- plify the experiment, the droplet transfer was captured F. LIU et al.: STUDY OF DROPLET TRANSFER CHARACTERISTICS AND WELD FORMATION WITH ER430LNb ... 242 Materiali in tehnologije / Materials and technology 57 (2023) 3, 241–248 Figure 1: Schematic diagram of the experimental system using the method of overlay welding on the plate workpiece. For the post-weld analysis, samples were cut using wire electro-discharge machining. For the optical-micro- scope testing, the sample was polished using emery pa- per with grit sizes of 600, 1000, 1500 and 2000. Finally, cloth polishing was done using 1-μm diamond paste to achieve a mirror finish of the weld cross-section. After polishing, the weld interface was etched with a Marble reactant etching solution (4 g CuSO 4 +20mLHCl+100 mL H 2 O) and the microstructure was observed with an optical microscope (BH200M). The crystal structure was characterized, using an X-ray diffractometer (XRD, D/MAX-2400) with Cu K radiation. The scanning range was from 30° to 100° in 2 at a scanning rate of 5°/min. A nanoindentation test (Nano indenter G200) was used to measure the hardness of welded joints, with a load of 80 mN. 3 RESULTS AND DISCUSSION 3.1 Three typical metal transfer patterns There were three typical metal transfer patterns ob- served during the GMAW using the ER430LNb ferritic stainless steel wire, namely the short circuit transfer, mix transfer and spray transfer. Short circuit transfer A droplet is short-circuited to the welding pool at low current and voltage before completing its growth. Under the effects of surface tension, gravity and electromag- netic forces, the droplet transfers to the base material, forming a short-circuit transfer. During the short-circuit transfer, a lot of spatter is ob- served (Figure 2e) as the arc voltage increases with the increasing welding current. In general, at low wire feed speeds, the droplet-transfer pattern in a GMAW process is either a short-circuit transfer or a particle transfer, de- pending on the arc voltage. Figure 2 shows the curves of the electrical parameter signals during the ER430LNb GMAW process within 1 s and the complete transfer of a droplet from wire tip generation, growth and then trans- fer into the welding pool. The I and U in the figures il- lustrate the average welding current and average arc volt- age. When the welding current is moderate, the short circuit transfer can be found to include three stages of short circuit, arc reignition, and droplet growth. The wire feed speed and welding current are relevant, and, as can be found in Figure 2, when the welding current in- creases, the wire feed speed increases as well, while the transfer period and arc initiation time for a single droplet gradually decrease. The droplet size affects the magnitude of gravity, arc force, etc. during the droplet-transfer process, resulting in different impacts of the liquid melt pool, thus affect- ing the melt pool flow forming. The change in the drop- let size during the droplet transfer from Figure 2d is shown in Figure 2g. From t 0 stot 0 + 0.152 s, the droplet diameter and size are marked in the voltage-waveform figure with the time variation. The droplet diameter is 2.0 mm at t 0 + 0.032 s. It increases to 2.3 mm and 2.6 mm after 0.33 s and 0.73 s, respectively, and reaches a maximum of 2.7 mm at t 0 + 0.141 s. The droplet size decreases after t 0 + 0.148 s to a diameter of 2.6 mm, which rapidly decreases to 2.0 mm after 0.04 s. During several droplet transfers within1so nt h e graph, the welding current and arc voltage patterns re- main largely unchanged, indicating a relatively stable welding process. The wire tip returns to 1.2 mm after 0.03 s and the melt droplet transfer process ends. In sum- mary, the short-circuit transfer is stable at a low wire feed speed and a suitable welding current. Figures 2 to 4 show that the electrical voltage signal does not go to zero at the time of the short circuit. Additionally, to smoothen the wave, the collected data of electrical signals are pro- cessed by mean filtering. The measured short circuit voltage increases after mean filtering, and it is not equal to zero when the short circuit occurs. As the proportion of short circuit transients is very small, it has little influ- ence on the analysis of electrical parameters. 3.1.1 Mix transfer The welding current of mix transfer is between those of short circuit transfer and spray transfer. The metal transfer patterns include both particle transfer and short circuit transfer, but the proportions vary randomly. With the increase in the welding current, the arc current-volt- age signal becomes more disordered between the short circuit transfer from Figure 3a and the mix transfer from Figure 3b, with both short-circuit and particle transfer. The welding current continues to increase and the drop- F. LIU et al.: STUDY OF DROPLET TRANSFER CHARACTERISTICS AND WELD FORMATION WITH ER430LNb ... Materiali in tehnologije / Materials and technology 57 (2023) 3, 241–248 243 Table 1: Main components of the welding wire and the base metal (w/%) Element C Si Mn P S Cr Ni Mo N Cu Nb Fe Welding wire 0.03 0.5 0.6 0.03 0.03 15.5–17.0 0.6 0.75 – 0.75 0.24–1.2 Balance Base metal 0.10 0.5 0.6 0.03 0.02 15.5–17.0 0.6 0.75 – 0.75 – Balance Table 2: Various welding parameters 1234567891 0 Welding speed (cm/min) 40 Welding current (A) 60 78 90 110 120 138 162 178 198 214 Arc voltage (V) 17.6 18 18.8 20.4 20.6 21.6 22.4 23.6 25.6 27 F. LIU et al.: STUDY OF DROPLET TRANSFER CHARACTERISTICS AND WELD FORMATION WITH ER430LNb ... 244 Materiali in tehnologije / Materials and technology 57 (2023) 3, 241–248 Figure 2: Droplet transfer and electric signals: a)I=60A,b)I=78A,c)I=90A,d)I=110A,e)I=120A,f)I=138A,g)change in droplet size at 110 A let for the complete particle transfer pattern is shown in Figure 3c. The molten droplet size decreases close to the wire diameter, and the molten droplet transfer occurs along the wire axis. The welding current continues to in- crease, and we see a fully particle-transfer pattern in Fig- ure 3c, with droplets falling along the axis of the wire. In addition, the droplet size decreases close to the wire di- ameter. Compared to the short circuit transfer, it can be seen from the voltage-current signal diagram that the fre- quency of the mix transfer increases significantly. Fig- ure 3c shows that the frequency of the particle transfer is very fast, and the actual number of transfers per second can reach 50. However, the reason why the periodic fre- quency of the electric signal is only 4–5 is that the insta- bility of the particle transfer causes a periodic short cir- cuit. As the welding current increases to 198 A, the droplet-transfer pattern changes from short circuit and particle transfer to a completely particle transfer. 3.1.2 Spray transfer As shown in Figure 4, when the welding current in- creases to 214 A, the droplet-transfer pattern changes from mix transfer to spray transfer. During the process of spray transfer, a droplet with a diameter smaller than that of the welding wire is generated from the tip of the weld- ing wire and it falls off. Before the previous droplet falls into the molten pool, the next droplet has been generated, starting to fall off. The transfer frequency of droplets is very high, and the number of transfers per second can reach hundreds of times. 3.2 Weld formation The weld formation at different GMAW parameters is shown in Figure 5. For a stable short circuit transfer, a good weld surface is demonstrated in Figure 5, with negligible welding spatter where the welding process is relatively stable. When the current increases to 162 A, the droplet impacts the surface of the liquid molten pool at the same time as the short circuit transfer so that the droplet transfer is unstable and the splash is large. When the welding current increases to 210 A or more, the width of the weld increases sharply, and the weld surface is badly formed, generating a lot of spatter and fumes. Different welding currents used for the weld formation are indicated in Figure 5d. It is worth mentioning that under each welding process parameter, the residual height of the weld does not change significantly. F. LIU et al.: STUDY OF DROPLET TRANSFER CHARACTERISTICS AND WELD FORMATION WITH ER430LNb ... Materiali in tehnologije / Materials and technology 57 (2023) 3, 241–248 245 Figure 4: Droplet transfer and electric signals at 214 A Figure 3: Droplet transfer and electric signals: a) I = 162 A, b) I = 178 A, c) I = 198 A F. LIU et al.: STUDY OF DROPLET TRANSFER CHARACTERISTICS AND WELD FORMATION WITH ER430LNb ... 246 Materiali in tehnologije / Materials and technology 57 (2023) 3, 241–248 Figure 5: Weld formation: a) short circuit transfer, b) mix transfer, c) spray transfer, d) weld formation at different welding currents Figure 6: Droplet transfer patterns and microstructure: a) droplet transfer patterns, b) microstructure for different droplet transfer patterns, c) XRD pattern of weld joints 3.3 Droplet transfer patterns, microstructure and drop- let transfer frequency With an increase in the welding parameters, the drop- let transfer pattern changes gradually. As shown in Fig- ure 6a, the droplet transfer pattern can be divided into three kinds: the short circuit transfer with small parame- ters, the mix transfer and the spray transfer. A set of pa- rameters, including 78 A, 178 A and 214 A, for each transfer pattern was selected to observe the micro- structure. It can be seen that the microstructure is coarse columnar ferrite, and the ferrite grain is also continu- ously coarse with the increasing welding current, as shown in Figure 6b. According to the XRD results shown in Figure 6c, the phase composition of the weld is a 100 % ferrite structure. The droplet transfer frequency is a very important pa- rameter, closely related to the welding efficiency and weld formation. A higher droplet transfer frequency causes a higher welding efficiency. With the increasing welding parameters, the droplet transfer frequency also changes gradually. For a weld formed of ferritic stainless steel, a small welding current with a moderate droplet transfer frequency is preferred. The droplet transfer fre- quency increases exponentially as shown in Figure 7. The regression fitting of the welding current to the drop- let transfer frequency was obtained using the Origin soft- ware, and the equation is as follows: (3-1) 3.4 Hardness test Five welding parameters were selected for hardness testing of three different droplet transfer patterns by a nanoindentation test. Figure 8 shows typical microhard- ness distributions with different welding currents for the three main welding zones: the base metal, HAZ and weld metal. A variation caused by nanoindentation was ob- served in the microhardness values from the base mate- rial to the weld metal. The highest hardness values were measured on the weld metal, between 3.5 GPa and 4.5 GPa. The hardness values of the HAZ were found to be between 2.2 GPa and 3.9 GPa. It should be underlined that the base metal has softer regions (1.8–2.3 GPa) than the HAZ. The in- crease in the hardness of the weld metal and base metal may be attributed to the changes in the microstructure through a relatively higher cooling rate due to the higher heat input during welding. The overall hardness of the welding zone (HAZ and weld metal) decreased due to the increase in the welding current. With the increasing welding current, a higher heat input is generated during welding. Therefore, the cooling takes place at a higher temperature. Thus, the changes in the volume ratio of the phases formed in the microstructure may cause an increase in the hardness. 4 CONCLUSIONS In this study, ER430LNb ferritic stainless steel used for gas metal arc welding was studied. The test results are summarized as follows: (1) During the GMAW using an ER430LNb ferritic stainless steel wire, the droplet transfer is a stable short circuit transfer at currents of less than 138 A. The drop- let transfer pattern is a mixed transfer at currents of around 162–198 A. And it is a spray transfer when the current is over approximately 214 A. (2) During the short circuit transfer stage, the droplet size is approximately 2–3 times the diameter of the welding wire. With an increase in the current, the droplet transfer gradually changes to particle transfer, and the droplet size decreases gradually. As the current increases further, the droplet transfer pattern is spray transfer, and the droplet size is smaller than the diameter of the weld- ing wire. (3) With the increase in the welding current, the cur- rent-voltage signal becomes more disordered, resulting F. LIU et al.: STUDY OF DROPLET TRANSFER CHARACTERISTICS AND WELD FORMATION WITH ER430LNb ... Materiali in tehnologije / Materials and technology 57 (2023) 3, 241–248 247 Figure 8: Hardness measurement results Figure 7: Non-linear fitted curves of droplet transfer frequency in more welding splash and fumes. For gas metal arc welding with ER430LNb ferritic stainless steel, a low welding current with a moderate droplet transfer fre- quency is preferred. (4) The weld microstructure of ER430LNb ferritic stainless steel indicates coarse columnar ferrite, and the grain size increases with the increase in the welding cur- rent. In addition, with a continuous increase in the weld- ing current, the droplet transfer frequency increases rap- idly and exponentially. (5) The hardness distribution values for the weld joints of the weld metal, HAZ and base metal are 3.5–4.5 GPa, 2.2–3.9 GPa and 1.8–2.3 GPa, respectively. The hardness in the welding zone (HAZ and weld metal) de- creases due to the welding current increase. Compliance with Ethical Standards Funding: This study was funded by the National Nat- ural Science Foundation of China (grant numbers 52274390 and 52075360). Conflicts of Interest The authors declare that they have no conflict of in- terest. 5 REFERENCES 1 K. A. Cashell, N. R. 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