{"?xml":{"@version":"1.0"},"edm:RDF":{"@xmlns:dc":"http://purl.org/dc/elements/1.1/","@xmlns:edm":"http://www.europeana.eu/schemas/edm/","@xmlns:wgs84_pos":"http://www.w3.org/2003/01/geo/wgs84_pos","@xmlns:foaf":"http://xmlns.com/foaf/0.1/","@xmlns:rdaGr2":"http://rdvocab.info/ElementsGr2","@xmlns:oai":"http://www.openarchives.org/OAI/2.0/","@xmlns:owl":"http://www.w3.org/2002/07/owl#","@xmlns:rdf":"http://www.w3.org/1999/02/22-rdf-syntax-ns#","@xmlns:ore":"http://www.openarchives.org/ore/terms/","@xmlns:skos":"http://www.w3.org/2004/02/skos/core#","@xmlns:dcterms":"http://purl.org/dc/terms/","edm:WebResource":[{"@rdf:about":"http://www.dlib.si/stream/URN:NBN:SI:doc-W4UU9JZ6/a2bfa922-997e-41be-8483-9b7778cb5c06/HTML","dcterms:extent":"18 KB"},{"@rdf:about":"http://www.dlib.si/stream/URN:NBN:SI:doc-W4UU9JZ6/eb9ee6e2-15e5-4fbb-b28e-01dcb3da1ad9/PDF","dcterms:extent":"654 KB"},{"@rdf:about":"http://www.dlib.si/stream/URN:NBN:SI:doc-W4UU9JZ6/f3eea191-4713-43d2-8f60-58bfdd224048/TEXT","dcterms:extent":"19 KB"}],"edm:TimeSpan":{"@rdf:about":"1998-2025","edm:begin":{"@xml:lang":"en","#text":"1998"},"edm:end":{"@xml:lang":"en","#text":"2025"}},"edm:ProvidedCHO":{"@rdf:about":"URN:NBN:SI:doc-W4UU9JZ6","dcterms:isPartOf":[{"@rdf:resource":"https://www.dlib.si/details/URN:NBN:SI:spr-KC6O72BG"},{"@xml:lang":"sl","#text":"Acta chimica slovenica"}],"dcterms:issued":"2001","dc:creator":["Kozlevčar, Bojan","Lah, Nina","Leban, Ivan","Šegedin, Primož","Žlindra, Daniel"],"dc:format":[{"@xml:lang":"sl","#text":"12 strani"},{"@xml:lang":"sl","#text":"številka:3"},{"@xml:lang":"sl","#text":"letnik:48"},{"@xml:lang":"sl","#text":"str. 363-374"}],"dc:identifier":["ISSN:1318-0207","COBISSID:23761413","URN:URN:NBN:SI:doc-W4UU9JZ6"],"dc:language":"en","dc:publisher":{"@xml:lang":"sl","#text":"Slovensko kemijsko društvo"},"dc:subject":[{"@xml:lang":"sl","#text":"bakrove spojine"},{"@xml:lang":"sl","#text":"IR spektroskopija"},{"@xml:lang":"sl","#text":"koordinacijske spojine"},{"@xml:lang":"sl","#text":"rentgenska difrakcija"},{"@xml:lang":"sl","#text":"struktura"}],"dcterms:temporal":{"@rdf:resource":"1998-2025"},"dc:title":{"@xml:lang":"sl","#text":"Copper(II) benzoates and acetates with 2-aminopyridine|"},"dc:description":[{"@xml:lang":"sl","#text":"Two monomeric and two dimeric copper(II) benzoate and acetate coordination compounds with 2-aminopyridine were synthesized. The crystal structures of benzoate compounds were determined by X-ray diffraction analyses. The monomeric benzoate form ?$Cu(O_2CC_6H_5)_2(2apy)_2$?(2apy=2-aminopyridine) is composed of trans oriented ligands around central copper(II) atom, where benzoates acts as asymmetrical chelates (Cu-O 1.97 and 2.65 L). On the other hand, dimeric form ?$Cu_2(O_2CC_6H_5)_4(apy)_2$? reveals paddle - wheel type structure where 2-aminopyridine acts as axial ligand via pyridine nitrogen atom. All compounds were characterized by standard physico-chemical methods and tested for their fungal mycelial growth retardation activity for wood fungi Tremetes versicolor and Antrodia vaillantii"},{"@xml:lang":"sl","#text":"Sintetizirani sta bili dve enojedrni in dve koordinacijski spojini bakrovega bnezoata in acetata z 2-aminopiridinom. Z rentgensko difrakcijsko analizo je bila določena kristalna struktura obeh benzoatnih spojin. V enojedrni benzoatni obliki ?$Cu(O_2CC_6H_5)_2(2apy)_2(2apy)=2-aminopiridin$?) so koordinirani ligandi v trans položaju okoli osrednjega bakrovega(II) atoma, kjer so benzoati asimetrični kelati (Cu-O 1.97 in 2.65 L). Po drugi strani dvojedrno obliko ?$Cu_2(O_2CC_6H_5)_4(2apy)_2$? predstavlja strukturni tip mlinskega kolesa z 2-aminopiridinom, ki se veže aksialno preko piridinskega dušikovega atoma. Vse spojine so bile karakterizirane s standardnimi fizikalno-kemijskimi metodami in testirane za njihovo zaviralno aktivnost pri rasti micelija lesnih gliv pisane ploskocevke in bele hišne gobe"}],"edm:type":"TEXT","dc:type":[{"@xml:lang":"sl","#text":"znanstveno časopisje"},{"@xml:lang":"en","#text":"journals"},{"@rdf:resource":"http://www.wikidata.org/entity/Q361785"}]},"ore:Aggregation":{"@rdf:about":"http://www.dlib.si/?URN=URN:NBN:SI:doc-W4UU9JZ6","edm:aggregatedCHO":{"@rdf:resource":"URN:NBN:SI:doc-W4UU9JZ6"},"edm:isShownBy":{"@rdf:resource":"http://www.dlib.si/stream/URN:NBN:SI:doc-W4UU9JZ6/eb9ee6e2-15e5-4fbb-b28e-01dcb3da1ad9/PDF"},"edm:rights":{"@rdf:resource":"http://creativecommons.org/licenses/by/4.0/"},"edm:provider":"Slovenian National E-content Aggregator","edm:intermediateProvider":{"@xml:lang":"en","#text":"National and University Library of Slovenia"},"edm:dataProvider":{"@xml:lang":"sl","#text":"Slovensko kemijsko društvo"},"edm:object":{"@rdf:resource":"http://www.dlib.si/streamdb/URN:NBN:SI:doc-W4UU9JZ6/maxi/edm"},"edm:isShownAt":{"@rdf:resource":"http://www.dlib.si/details/URN:NBN:SI:doc-W4UU9JZ6"}}}}