1675 KB33 KB201420242024Koncilja, Maksštevilka:1letnik:1111 str.COBISSID_HOST:197160451ISSN:2385-8567URN:URN:NBN:SI:doc-F34D282HslZaložba Fakultete za matematiko in fiziko Univerze v LjubljaniMatrikacharge regulationelectrostaticselektrostatikamacromoleculesmakromolekuleregulacija nabojatitracijatitrationRegulacija naboja in robni pogoji v elektrostatiki|Some macromolecules can donate and accept acidic and basic groups. The charge regulation depends of pH value and local potential, it affects some natural processes, such as the passage of DNA through nanopores. Charge regulation is exploited in industry, including the production of polyelectrolyte materials. In this paper, charge regulation is introduced with “chemical” phenomenological interpretation and a “physical” statistical mechanical approach. Introduction of the charge regulation is followed by the description of charge regulated macromolecules in an ion solution, starting with the example of two charge regulated macromolecules. The final part focuses on the many-body problem of macromolecules, which can be described differently based on the physical circumstances. When dealing with static macromolecules the cell model is used, whereas under alternative conditions a collective approach of moving macromolecules is utilizedNekatere makromolekule so sposobne titriranja, saj lahko oddajo in prejmejo kislinske in bazične skupine. Regulacija naboja, ki je odvisna od vrednosti pH in lokalnega potenciala, vpliva na nekatere naravne procese kot na primer potovanje DNA skozi nanopore. Ravno tako se regulacijo naboja izkorišča v industriji, med drugim za oblikovanje materialov iz polielektrolitov. V članku je regulacija naboja vpeljana s pomočjo “kemijske” fenomenološke interpretacije in s “fizikalnim” statistično mehanskim pristopom. Sledi opis makromolekul z reguliranim nabojem v raztopini ionov, na primeru dveh makromolekul z regulariziranim nabojem. Nadaljujemo z večdelčnim problemom makromolekul v raztopini, ki ga lahko glede na fizikalne razmere opišemo bodisi z uporabo celičnega modela, za statične raztopine, bodisi s kolektivnim opisom gibljivih makromolekulTEXTznanstveno časopisjejournalsSlovenian National E-content AggregatorNational and University Library of Slovenia