{"?xml":{"@version":"1.0"},"edm:RDF":{"@xmlns:dc":"http://purl.org/dc/elements/1.1/","@xmlns:edm":"http://www.europeana.eu/schemas/edm/","@xmlns:wgs84_pos":"http://www.w3.org/2003/01/geo/wgs84_pos","@xmlns:foaf":"http://xmlns.com/foaf/0.1/","@xmlns:rdaGr2":"http://rdvocab.info/ElementsGr2","@xmlns:oai":"http://www.openarchives.org/OAI/2.0/","@xmlns:owl":"http://www.w3.org/2002/07/owl#","@xmlns:rdf":"http://www.w3.org/1999/02/22-rdf-syntax-ns#","@xmlns:ore":"http://www.openarchives.org/ore/terms/","@xmlns:skos":"http://www.w3.org/2004/02/skos/core#","@xmlns:dcterms":"http://purl.org/dc/terms/","edm:WebResource":[{"@rdf:about":"http://www.dlib.si/stream/URN:NBN:SI:DOC-67KX4MSM/aff4db66-74c1-441b-9e3d-80725d394a15/HTML","dcterms:extent":"11 KB"},{"@rdf:about":"http://www.dlib.si/stream/URN:NBN:SI:DOC-67KX4MSM/9129cef3-ef8e-4476-b29b-59d9df815488/PDF","dcterms:extent":"132 KB"},{"@rdf:about":"http://www.dlib.si/stream/URN:NBN:SI:DOC-67KX4MSM/6fceb9c2-95df-4425-bb27-543a88bbece4/TEXT","dcterms:extent":"10 KB"}],"edm:TimeSpan":{"@rdf:about":"2000-2024","edm:begin":{"@xml:lang":"en","#text":"2000"},"edm:end":{"@xml:lang":"en","#text":"2024"}},"edm:ProvidedCHO":{"@rdf:about":"URN:NBN:SI:DOC-67KX4MSM","dcterms:isPartOf":[{"@rdf:resource":"https://www.dlib.si/details/urn:nbn:si:spr-ihg6vo21"},{"@xml:lang":"sl","#text":"Materiali in tehnologije"}],"dcterms:issued":"2003","dc:creator":["Orel, Boris","Švegl, Franc"],"dc:format":[{"@xml:lang":"sl","#text":"številka:1/2"},{"@xml:lang":"sl","#text":"3 strani"},{"@xml:lang":"sl","#text":"letnik:37"},{"@xml:lang":"sl","#text":"str. 29-31"}],"dc:identifier":["ISSN:1580-2949","COBISSID:824167","URN:URN:NBN:SI:doc-67KX4MSM"],"dc:language":"en","dc:publisher":{"@xml:lang":"sl","#text":"Inštitut za kovinske materiale in tehnologije"},"dc:subject":[{"@xml:lang":"sl","#text":"bakrov oksid"},{"@xml:lang":"sl","#text":"Berremanov pojav"},{"@xml:lang":"sl","#text":"FTIR spektroskopija"},{"@xml:lang":"sl","#text":"optične lastnosti"},{"@xml:lang":"sl","#text":"tanke plasti"}],"dcterms:temporal":{"@rdf:resource":"2000-2024"},"dc:title":{"@xml:lang":"sl","#text":"The application of FT-IR reflection-absorption spectroscopy for determining the textural properties of copper oxide thin films| Uporaba FT-IR refleksijsko-absorpcijske spektroskopije za določitev teksturnih lastnosti tankih plasti bakrovega oksida|"},"dc:description":[{"@xml:lang":"sl","#text":"Optical CuO coatings were deposited on different substrates with the wet chemistry route using a dip-coating technique. Studies of microstructure with SEM and TEM methods revealed that the films consist of spherical particles with diameters of about 50 nm. It was found that the thicker films exhibit a denser microstructure. From the determination of longitudinal optical modes (LO) of the CuO lattice by FTIR NGIA reflection-absorption spectroscopy and the phenomenon of the Berroman effect a method for qualitative and quantitative determination of the compactness of thin films was developed. The calculation of the optical constants (refractive index and absorption coefficient) for films having different thickness showed that the calculated refractive indices and the frequency shift of the CuO modes depend on the coating thickness and the density of the films. These results are in agreement with the observations of the microstructure and enable a quantitative estimation of the compactness of the CuO coatings"},{"@xml:lang":"sl","#text":"Tanke plasti bakrovega (II) oksida smo pripravili po postopku mokre kemije iz bakrovega (II) acetata monohidrata in citronske kisline s tehniko potapljanja. Študij mikrostrukture različno debelih plasti CuO z elektronsko mikroskopijo je pokazal, da so sestavljene iz sferičnih delcev s premerom okrog 50 nm. Pri povečanju debeline smo opazili zgostitev mikrostrukture. Z uporabo FT-IR NGIA refleksijsko-absorpcijske tehnike smo določili longitudinalna LO-nihanja kristalne rešetke CuO in na podlagi Berremanovega pojava razvili metodo za kvalitativno in kvantitativno določitev kompaktnosti strukture tankih plasti. Iz izmerjenih FT-IR NGIA-spektrov različno debelih plasti smo izračunali lomne količnike in dielektrične funkcije, ter ugotovili, da lomni količnik narašča z povečanjem debeline tanke plasti. Dobljeni rezultati potrjujejo ugotovitve študija mikrostrukture in omogočajo kvantitativno ocenitev kompaktnosti tankih plasti bakrovega oskida"}],"edm:type":"TEXT","dc:type":[{"@xml:lang":"sl","#text":"znanstveno časopisje"},{"@xml:lang":"en","#text":"journals"},{"@rdf:resource":"http://www.wikidata.org/entity/Q361785"}]},"ore:Aggregation":{"@rdf:about":"http://www.dlib.si/?URN=URN:NBN:SI:DOC-67KX4MSM","edm:aggregatedCHO":{"@rdf:resource":"URN:NBN:SI:DOC-67KX4MSM"},"edm:isShownBy":{"@rdf:resource":"http://www.dlib.si/stream/URN:NBN:SI:DOC-67KX4MSM/9129cef3-ef8e-4476-b29b-59d9df815488/PDF"},"edm:rights":{"@rdf:resource":"http://rightsstatements.org/vocab/InC/1.0/"},"edm:provider":"Slovenian National E-content Aggregator","edm:intermediateProvider":{"@xml:lang":"en","#text":"National and University Library of Slovenia"},"edm:dataProvider":{"@xml:lang":"sl","#text":"Inštitut za kovinske materiale in tehnologije"},"edm:object":{"@rdf:resource":"http://www.dlib.si/streamdb/URN:NBN:SI:DOC-67KX4MSM/maxi/edm"},"edm:isShownAt":{"@rdf:resource":"http://www.dlib.si/details/URN:NBN:SI:DOC-67KX4MSM"}}}}